Small chemical plant
A small Stretford reactor for scrubbing H2S from geothermal steam
Source: Wikimedia Commons

The Stretford process was developed during the late 1950s to remove hydrogen sulfide (H2S) from town gas. It was the first liquid phase oxidation process for converting H2S into sulfur to gain widespread commercial acceptance.[1] Developed by Tom Nicklin[a]Nicklin had previously developed a process for improving the
conversion of coal to coal gas, known as the Rochdale process.
of the North Western Gas BoardThe North Western Gas Board (NWGB) was a state-owned utility area gas board providing gas for light and heat to industries and homes in the north-west of England. (NWGB) and the Clayton Aniline Company, in Manchester, England, the name of the process was derived from the location of the NWGB’s laboratories in Stretford.

The process uses reduction-oxidation (redox) chemistry to oxidise the H2S into elemental sulfur, in an alkaline solution containing vanadium as an oxygen carrier.[2]

The process earned the NWGB a Queen’s Award to Industry in 1968. Although it was used in the gas industry for only a relatively short time, the process was licensed by the NWGB and used successfully in a variety of industries worldwide.[3][b]The North Western Gas Board became part of British Gas in 1973 as a result of the Gas Act 1972. At the height of its popularity during the 1970s there were more a dozen companies offering the Stretford technology. By 1987 about 170 Stretford plants had been built worldwide, and more than 100 were still operating in 1992, capable of removing 400,000 tons of sulfur per year.[4] The first US plant was commissioned in 1971 at Long Beach, California, to process the gas from offshore oil wells.[5]

The Stretford process exhibited some inherent inefficiences; it was slow, and it produced relatively high amounts of a thiosulfate byproduct. It was replaced by more efficient chelated-iron processes from the mid-1980s onwards.[1]

Citations



Bibliography


Jessup, J. (1994). Gas in the NorthWest: 1949–1994. British Gas Northwestern.
Kohl, A. L., & Nielsen, R. (1999). Gas Purification (5th ed.). Gulf Professional Publishing.
Korens, N., Simbeck, D. R., & Wilhelm, D. J. (2002, December). Process Screening Analysis of Alternative Gas Treating and Sulfur Removal for Gasification. SFA Pacific. Retrieved from https://www.netl.doe.gov/File%20Library/Research/Coal/energy%20systems/gasification/pubs/SFA-Pacific_Process-Screening-Analysis_Dec-2002.pdf
Staff writer. (1971). ...briefly... Chemical & Process Engineering, 52, 7.

Notes

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a. Nicklin had previously developed a process for improving the
conversion of coal to coal gas, known as the Rochdale process.
b. The North Western Gas Board became part of British Gas in 1973 as a result of the Gas Act 1972.